Ammonia Storage in lithium fullerides


ammonia-storageAmmonia has been proposed as an indirect hydrogen carrier, as solid-state ammonia-storage could be easier than directly absorbing hydrogen in materials. Here we investigate the structural evolution of hyper-ammoniated lithium fullerides (ND3)yLi6C60 during ammonia desorption, using in-situ high intensity neutron powder diffraction. In (ND3)yLi6C60, ammonia molecules are stored in their neutral state inside the inter-fullerene interstices and are coordinated to the intercalated Li ions, forming Li–ND3 clusters. Li6C60 absorbs up to 36.8 wt% ND3, which corresponds to ~14 ammonia molecules per C60. The ammonia release, studied in-situ and ex-situ by manometric analyses and differential scanning calorimetry, takes place in two main steps, at 350–410 K and 500–540 K, respectively. This corresponds to two clear 1st order phase transitions and the absorption process is partially reversible. These findings suggest that the system could be a good candidate for ammonia-storage applications.

Reproduced with permission. Copyright 2015, Royal Society of Chemistry

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